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Cobalt Complexes

아래 품번을 누르시면 상세 정보를 보실 수 있습니다.

Counter Ion Cl PF6 TFSI B(CN)4
Complex
Co(bpy)3

Standard material:
DN-C15
DN-C16

Standard material:
DN-C01
DN-C02
Standard material:
DN-C13
DN-C14
Standard material:
DN-C03
DN-C04
Co(phen)3 Standard material:
DN-C17
DN-C18
Standard material:
DN-C07
DN-C08
Standard material:
DN-C21
DN-C22
Available on demand
Co(bpy-pz)2 Standard material:
DN-C19
DN-C20
Standard material:
DN-C09
DN-C10
Available on demand Available on demand

 

Performance-boosting additives

DN-X04
tris(4-methoxyphenyl)amine

 

Full Name: Tris(4-methoxyphenyl) amine은 작고 활용도가 높은 redox-active 분자로 액체 및 고체형 태양전지(solid-state solar cell) 모두에 사용 가능합니다. 액체 전해질을 사용하는 DSSC 태양전지에서 빠른 염료 재생을 위해 금속 기반의 redox couple과 함께 사용할 수 있으며 이는 10% 이상의 효율을 쉽게 얻을 수 있습니다. 고체형 태양전지에서 단독 또는 P3HT와 같은 다른 물질과 결합하여 저비용의 정공수송물질(hole transport material (HTM))로 사용될 수 있습니다.
Full name: tris(4-methoxyphenyl)amine
Alternative name: TPAA, TAA, tris(p-anisyl)amine, tris(para-anisyl)amine
CAS number: 13050-56-1
Typical properties:
Eox (DCM) = 0.85 V vs. NHE
MW: 335.40 g/mol
Reference: J. Phys. Chem. C 2012, 116, 18070-18078, DOI: 10.1021/jp3052449
Chem. Mater., 2001, 13 (11), pp 4105-4111, DOI: 10.1021/cm010281p
Nature Commun. 7 (2016) 13934, DOI: 10.1038/ncomms13934
Order amount:

1g, 5g

 

Water-soluble Cobalt-Complexes

DN-C15
Co(bpy)3Cl2 · 5 H2O

 

Full Name: Tris(2,2'-bipyridine)cobalt(II) dichloride pentahydrate
CAS number: 14855-51-7
Properties:
E02+/3+(H2O): 0.33 V vs NHE
MW: 688.47 g/mol
Reference: Phys. Chem. Chem. Phys., 2016, Advance Article, DOI: 10.1039/C6CP00264A
Additional information:

water-based DSSC에서의 사용을 위해 코발트 착화합물 DN-C15~ DN-C18은 염료 DN-F05M과 결합시킬 수 있습니다.

  Order amount: 1g, 5g, 25g

 

DN-C16
Co(bpy)3Cl3 · 4 H2O

 

Full Name: Tris(2,2'-bipyridine)cobalt(III) trichloride tetrahydrate
CAS number: 19488-82-5
Properties:
E02+/3+(H2O): 0.33 V vs NHE
MW: 705.91 g/mol
Reference: Phys. Chem. Chem. Phys., 2016, Advance Article, DOI: 10.1039/C6CP00264A
Additional information: water-based DSSC에서의 사용을 위해 코발트 착화합물 DN-C15~ DN-C18은 염료 DN-F05M과 결합시킬 수 있습니다.
Order amount: 1g, 5g, 25g

 

DN-C17
Co(phen)3Cl2· 2 H2O

 

Full Name: Tris(1,10-phenanthroline)cobalt(II) dichloride dihydrate
CAS number: 15136-98-8
Properties:
E02+/3+(H2O): 0.33 V vs NHE
MW: 706.49 g/mol
Reference: Phys. Chem. Chem. Phys., 2016, Advance Article, DOI: 10.1039/C6CP00264A
Additional information: water-based DSSC에서의 사용을 위해 코발트 착화합물 DN-C15~ DN-C18은 염료 DN-F05M과 결합시킬 수 있습니다.
Order amount: 1g, 5g, 25g

 

DN-C18
Co(phen)3Cl3· 5H2O

 

Full Name: Tris(1,10-phenanthroline)cobalt(III) trichloride pentahydrate
CAS number: 15406-83-4
Properties:
E02+/3+(H2O): 0.33 V vs NHE
MW: 795.99 g/mol
Reference: Phys. Chem. Chem. Phys., 2016, Advance Article,DOI: 10.1039/C6CP00264A
Additional information: water-based DSSC에서의 사용을 위해 코발트 착화합물 DN-C15~ DN-C18은 염료 DN-F05M과 결합시킬 수 있습니다.
Order amount: 1g, 5g, 25g

DN-C19
Co(bpy-pz)2Cl2· 2H2O

 

Full Name: bis(6-(1H-pyrazol-1-yl)-2,2'-bipyridine)cobalt(II) dichloride dihydrate
Properties:
E02+/3+(H2O): 0.60 V vs NHE
MW: 610.37 g/mol
Reference: Phys. Chem. Chem. Phys., 2016, Advance Article, DOI: 10.1039/C6CP00264A
Application example:

water-based DSSC에서 염료 DN-F05M과 결합한 DN-C19/20 산화환원 쌍은 최대 5.7%의 전력 변환 효율에 도달했습니다. C15/C16과 C17/C18과 비교하여 C19/C20의 높은 산화화원전위가 장치의 광전압을 증가시킬 수 있습니다.

Order amount: 250mg, 1g

 

DN-C20
Co(bpy-pz)2Cl3· 2H2O

 

Full Name: bis(6-(1H-pyrazol-1-yl)-2,2'-bipyridine)cobalt(III) trichloride dihydrate
Properties:
E02+/3+(H2O): 0.60 V vs NHE
MW: 645.82 g/mol
Reference: Phys. Chem. Chem. Phys., 2016, Advance Article, DOI: 10.1039/C6CP00264A
Application example:

water-based DSSC에서 염료 DN-F05M과 결합한 DN-C19/20 산화환원 쌍은 최대 5.7%의 전력 변환 효율에 도달했습니다. C15/C16과 C17/C18과 비교하여 C19/C20의 높은 산화화원전위가 장치의 광전압을 증가시킬 수 있습니다.

Order amount: 250mg, 1g

 

Cobalt-complexes for increased open circuit voltage

DN-C07
Co(phen)3(PF6)2

 

Full Name: Tris(1,10-phenanthroline)cobalt bis(hexafluorophosphate)
CAS number: 31876-74-1
Properties:
E02+/3+: 0.61 V vs NHE
MW: 889.49 g/mol
Reference: Feldt et al., Phys. Chem. Chem. Phys., 2013, 15, 7087-7097
Order amount: 1g, 5g, 25g


DN-C08
Co(phen)3(PF6)2

 

Full Name: Tris(1,10-phenanthroline)cobalt bis(hexafluorophosphate)
CAS number: 31876-74-1
Properties:
E02+/3+: 0.61 V vs NHE
MW: 889.49 g/mol
Reference: Feldt et al., Phys. Chem. Chem. Phys., 2013, 15, 7087-7097
Order amount: 1g, 5g, 25g


DN-C21
Co(phen)3(TFSI)2

 

Full Name: Tris(1,10-phenanthroline)cobalt(II)di(bis(trifluoromethane)sulfonimide)
Properties:
MW : 1159.83 g/mol
Order amount: 주문 시 공급 가능


DN-C22
Co(phen)3(TFSI)3

 

Full Name: Tris(1,10-phenanthroline)cobalt(III)tri(bis(trifluoromethane)sulfonimide)
Properties:
MW : 1439.97 g/mol
Order amount: 주문 시 공급 가능

 


DN-C09
Co(bpy-pz)2(PF6)2

 

Full Name: Bis(6-(1H-pyrazol-1-yl)-2,2'-bipyridine)cobalt bis(hexafluorophosphate)
CAS number: 312322-08-0
Properties:
E02+/3+: 0.86 V vs NHE
MW: 793.36 g/mol
Reference: Feldt et al., Phys. Chem. Chem. Phys., 2013, 15, 7087-7097
Yum, J.-H. et al. Nat. Commun. 3:631 DOI: 10.1038/ncomms1655 (2012)
Order amount: 1g, 5g, 25g

 


DN-C10
Co(bpy-pz)2(PF6)3

 

Full Name: Bis(6-(1H-pyrazol-1-yl)-2,2'-bipyridine)cobalt tris(hexafluorophosphate)
CAS number: 1346417-60-4
Properties:
E02+/3+: 0.86 V vs NHE
MW: 983.33 g/mol
Reference:

Feldt et al., Phys. Chem. Chem. Phys., 2013, 15, 7087-7097

Yum, J.-H. et al. Nat. Commun. 3:631 DOI: 10.1038/ncomms1655 (2012)

Order amount: 1g, 5g, 25g

Original Cobalt-Complexes

DN-C01
Co(bpy)3(PF6)2

 

Full Name: Tris-(2,2’-bipyridine)cobalt(II) di(hexafluorophosphate)
CAS number: 79151-78-3
Properties:
MW: 817.13 g/mol
Reference: Feldt et al., J. Am. Chem. Soc., 2010, 132, 16714
Order amount: 1g, 5g, 25g

 

DN-C02
Co(bpy)3(PF6)3

 

Full Name: Tris-(2,2’-bipyridine)cobalt(III) tri(hexafluorophosphate)
CAS number: 28277-53-4
Properties:
MW: 962.37 g/mol
Reference: Feldt et al., J. Am. Chem. Soc., 2010, 132, 16714
Order amount: 1g, 5g, 25g

 

 

DN-C03
Co(bpy)3(B(CN)4)2

 

Full Name: Tris-(2,2’-bipyridine)cobalt(II) di(tetracyanoborate)
CAS number: 1350928-19-6
Properties:
MW: 757.25 g/mol
Reference: Yella, A. et al., Science 2011, 334, 629
Order amount: 주문 시 공급 가능

 

 

DN-C04
Co(bpy)3(B(CN)4)3

 

Full Name: Tris-(2,2’-bipyridine)cobalt(III) tri(tetracyanoborate)
CAS number: 1350928-20-9
Properties:
MW: 872.13 g/mol
Reference: Yella, A. et al., Science 2011, 334, 629
Order amount: 주문 시 공급 가능

DN-C13
Co(bpy)3(TFSI)2

 

Full Name: Tris-(2,2'-bipyridine)cobalt(II)di(bis(trifluoromethane)sulfonimide)
CAS number: 1353745-90-0
Properties:
E02+/3+: 0.57 V vs NHE
MW: 1087.8 g/mol
Reference: Yella, A., et al. Chem. Mater., 2013, 25 (13), pp 2733-2739 DOI: 10.1021/cm401593b
Kavan, L., et al. Electrochimica Acta, 2016, vol. 195, p. 34-42 DOI: 10.1016/j.electacta.2016.02.097
Order amount: 1g, 5g, 25g

 

DN-C14
Co(bpy)3(TFSI)3

 

Full Name: Tris-(2,2'-bipyridine)cobalt(III)tri(bis(trifluoromethane)sulfonimide)
CAS number: 1353745-91-1
Properties:
E02+/3+: 0.57 V vs NHE
MW: 1367.9 g/mol
Reference: Yella, A., et al. Chem. Mater., 2013, 25 (13), pp 2733-2739 DOI: 10.1021/cm401593b
Kavan, L., et al. Electrochimica Acta, 2016, vol. 195, p. 34-42 DOI: 10.1016/j.electacta.2016.02.097
Order amount: 1g, 5g, 25g